Wake Forest University 
 
Chem 116 VSEPR Handout 
 
Number of Electron Groups
Electron Group Geometry
Number of Lone Pairs
VSEPR Notation
Molecular Geometry
Ideal Bond Angles
Hybridization
Example
2
linear
0
AX2
"linear"
180°
sp
HCN
3
trigonal planar
0
AX3
"trigonal planar"
 120°
 sp2
 BF3
 
 
1
AX2E
"bent"
<120°
sp2
SO2
4
tetrahedral
0
AX4
"tetrahedral"
109.5°
sp3
CH4
 
 
 1
 AX3E
 
"pyramidal"
< 109.5° 
 sp3
NH3 
 
 
2
 AX2E2
"bent"
< 109.5°
sp3
H2O
 trigonal bipyramidal
 0
AX5 
"trigonal bipyramidal"
90°, 120°
 sp3d
PF5 
 
 
1
AX4E
"see-saw"
< 90°, <120°
sp3d
SF4
 
 
2
AX3E2
"T-shaped"
< 90°
sp3d
ClF3
 
 
3
AX2E3
"linear"
180°
sp3d
XeF2
 
 
 0
 AX6
 
"octahedral"
90° 
sp3d2 
SF6 
 6
octahedral 
1
AX5E
"square pyramidal"
< 90°
sp3d2
BrF5
 
 
2
AX4E2
"square planar"
90°
sp3d2
XeF4
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


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